Kandambeth, Sharath ; Shinde, Digambar Balaji ; Panda, Manas K. ; Lukose, Binit ; Heine, Thomas ; Banerjee, Rahul (2013) Enhancement of Chemical Stability and Crystallinity in Porphyrin-Containing Covalent Organic Frameworks by Intramolecular Hydrogen Bonds Angewandte Chemie International Edition, 52 (49). pp. 13052-13056. ISSN 1433-7851
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Official URL: http://doi.org/10.1002/anie.201306775
Related URL: http://dx.doi.org/10.1002/anie.201306775
Abstract
A strong bond: A strategy based on intramolecular hydrogen‐binding interactions in 2D covalent organic frameworks (COFs) is shown to improve the crystallinity, porosity, and chemical stability of the material (see picture). The concept is validated by removing the hydrogen‐bonding interaction in the methoxy analog which showed a lower stability and crystallinity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc.. |
| Keywords: | Covalent Organic Frameworks; Hydrogen Bonds; Mesoporous Materials; Porphyrinoids; Tautomerism. |
| ID Code: | 115847 |
| Deposited On: | 16 Mar 2021 09:15 |
| Last Modified: | 16 Mar 2021 09:15 |
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