Mallick, Arijit ; Garai, Bikash ; Díaz, David Díaz ; Banerjee, Rahul (2013) Hydrolytic Conversion of a Metal-Organic Polyhedron into a Metal-Organic Framework Angewandte Chemie International Edition, 52 (51). pp. 13755-13759. ISSN 14337851
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Official URL: http://doi.org/10.1002/anie.201307486
Related URL: http://dx.doi.org/10.1002/anie.201307486
Abstract
Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal–organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc.. |
| Keywords: | Cage Compounds; Crystal Engineering; Hydrophobic Effect; Metal–Organic Frameworks; Self‐Assembly. |
| ID Code: | 115846 |
| Deposited On: | 16 Mar 2021 09:15 |
| Last Modified: | 16 Mar 2021 09:15 |
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