The first structurally alternating copper(II) chain with alternate single end-on and end-to-end azido bridging: a synthesis, crystal structure, and low-temperature magnetic study

Mukherjee, Partha Sarathi ; Maji, Tapas Kumar ; Mostafa, Golam ; Mallah, Talal ; Chaudhuri, Nirmalendu Ray (2000) The first structurally alternating copper(II) chain with alternate single end-on and end-to-end azido bridging: a synthesis, crystal structure, and low-temperature magnetic study Inorganic Chemistry, 39 (22). pp. 5147-5150. ISSN 0020-1669

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Official URL: https://pubs.acs.org/doi/abs/10.1021/ic000507a

Related URL: http://dx.doi.org/10.1021/ic000507a

Abstract

A novel 1-D chain of Cu(II) with alternate single end-on and single end-to-end azido bridge having a very high Cu−N3(1,1)−Cu bond angle (129.98°) has been synthesized and characterized, which shows an intrachain antiferromagnetic interaction (J = −11.5 cm-1 for end-on bridge and −2.7 cm-1 for end-to-end bridge).

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