Total synthesis of (−)-radicamine B

Gurjar, Mukund K. ; Borhade, Ramdas G. ; Puranik, Vedavati G. ; Ramana, C. V. (2006) Total synthesis of (−)-radicamine B Tetrahedron Letters, 47 (39). pp. 6979-6981. ISSN 0040-4039

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The synthesis of a chiral cyclic nitrone with l-arabino configuration and its application in the total synthesis of radicamine B is reported. An agreement in the spectral data with natural radicamine B but specific rotation with an opposite sign warranted a revision of the absolute configuration of radicamine B.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Polyhydroxy Pyrrolidine Alkaloids; Radicamine B; Codonopsinine; Cyclic Nitrone; Grignard Addition
ID Code:11478
Deposited On:16 Nov 2010 13:54
Last Modified:02 Jun 2011 09:42

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