First observation of a ferromagnetic interaction through an end-to-end azido bridging pathway in a 1D copper(II) system

Maji, Tapas Kumar ; Mukherjee, Partha Sarathi ; Chaudhuri, Nirmalendu Ray ; Mostafa, Golam ; Mallah, Talal ; Cano-Boquera, Joan (2001) First observation of a ferromagnetic interaction through an end-to-end azido bridging pathway in a 1D copper(II) system Chemical Communications (11). pp. 1012-1013. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2001...

Related URL: http://dx.doi.org/10.1039/B100529O

Abstract

A novel one-dimensional copper(II) compound [Cu(L)(μ1,3-N3)(ClO4)]n [L = tridentate Schiff base, formed by condensation of pyridine-2-aldehyde and 1-(2-aminoethyl)piperidine] has been synthesized and structurally characterized; it exhibits ferromagnetic interaction via end-to-end azido (μ1,3-N3) linkages, as rationalised by DFT calculation.

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