A three-dimensional honeycomb-like network constructed with novel “sinusoidal” one-dimensional chains via hydrogen bonding and π−π interactions

Ghoshal, Debajyoti ; Maji, Tapas Kumar ; Mostafa, Golam ; Lu, Tian-Huey ; Chaudhuri, Nirmalendu Ray (2003) A three-dimensional honeycomb-like network constructed with novel “sinusoidal” one-dimensional chains via hydrogen bonding and π−π interactions Crystal Growth & Design, 3 (1). pp. 9-11. ISSN 1528-7483

Full text not available from this repository.

Official URL: https://pubs.acs.org/doi/abs/10.1021/cg025574p

Related URL: http://dx.doi.org/10.1021/cg025574p

Abstract

A one pot reaction of MnCl2, acetylene dicarboxylate (C4O22-), and 1,2-bis(4-pyridyl)ethane (bpe) leads to a compound formulated as [{Mn(bpe)(H2O)4}(C4O44.5H2O] and has been shown by single crystal structure analysis to be a three-dimensional network with hexagonal and rhombohedral channels encapsulating C4O42- and water molecules, constructed by the one-dimensional “sinusoidal” [Mn(bpe)(H2O)4]n2+ cationic chains through extensive hydrogen-bonding and π−π interactions.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:114729
Deposited On:29 May 2018 11:18
Last Modified:29 May 2018 11:18

Repository Staff Only: item control page