Expanding and shrinking porous modulation based on pillared-layer coordination polymers showing selective guest adsorption

Maji, Tapas Kumar ; Uemura, Kazuhiro ; Chang, Ho-Chol ; Matsuda, Ryotaro ; Kitagawa, Susumu (2004) Expanding and shrinking porous modulation based on pillared-layer coordination polymers showing selective guest adsorption Angewandte Chemie International Edition, 43 (25). pp. 3269-3272. ISSN 1433-7851

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Official URL: https://onlinelibrary.wiley.com/doi/abs/10.1002/an...

Related URL: http://dx.doi.org/10.1002/anie.200453923

Abstract

Rationally designed and synthesized, two novel pillar‐layered 3D microporous frameworks {[Cd(pzdc)(azpy)]⋅2 H2O}n (1, left) and {[Cd(pzdc)(bpee)]⋅1.5 H2O}n (2, right) have high thermal stability and highly selective adsorption properties. Removal of guest water molecules results in the expansion of 1 but the contraction of 2.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Adsorption; Cadmium; Coordination Polymers; Host–Guest Systems; Microporous Materials
ID Code:114718
Deposited On:29 May 2018 11:04
Last Modified:29 May 2018 11:04

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