A heterometallic polymeric complex: [Cu2(N3)2(medpt)2{Ni(CN)4}]N[medpt is bis(3-aminopropyl)methylamine]

Ghoshal, Debajyoti ; Maji, Tapas Kumar ; Rosair, Georgina ; Mostafa, Golam (2004) A heterometallic polymeric complex: [Cu2(N3)2(medpt)2{Ni(CN)4}]N[medpt is bis(3-aminopropyl)methylamine] Acta Crystallographica Section C, 60 (5). m212-m214. ISSN 0108-2701

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Official URL: http://journals.iucr.org/c/issues/2004/05/00/sk171...

Related URL: http://dx.doi.org/10.1107/S0108270104007152


The structure of the title compound, catena-poly­[[di-Μ-azido-κ4N1:N1-bis­[[bis(3-amino­propyl)­methyl­amine-κ3N]copper(II)]]-Μ-cyano-[di­cyano­nickel(II)]-Μ-cyano], [Cu2(N3)2(medpt)2{Ni(CN)4}]n [medpt is bis(3-amino­propyl)­methyl­amine, C7H19N2] or [Cu2Ni(CN)4(N3)2(C7H2N3)2]2, is a one-dimensional heterometallic covalent chain where Ni(CN)22 functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.

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