Ghoshal, Debajyoti ; Maji, Tapas Kumar ; Rosair, Georgina ; Mostafa, Golam (2004) A heterometallic polymeric complex: [Cu2(N3)2(medpt)2{Ni(CN)4}]N[medpt is bis(3-aminopropyl)methylamine] Acta Crystallographica Section C, 60 (5). m212-m214. ISSN 0108-2701
Full text not available from this repository.
Official URL: http://journals.iucr.org/c/issues/2004/05/00/sk171...
Related URL: http://dx.doi.org/10.1107/S0108270104007152
Abstract
The structure of the title compound, catena-poly[[di-Μ-azido-κ4N1:N1-bis[[bis(3-aminopropyl)methylamine-κ3N]copper(II)]]-Μ-cyano-[dicyanonickel(II)]-Μ-cyano], [Cu2(N3)2(medpt)2{Ni(CN)4}]n [medpt is bis(3-aminopropyl)methylamine, C7H19N2] or [Cu2Ni(CN)4(N3)2(C7H2N3)2]2, is a one-dimensional heterometallic covalent chain where Ni(CN)22 functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to International Union of Crystallography. |
| ID Code: | 114708 |
| Deposited On: | 29 May 2018 06:44 |
| Last Modified: | 29 May 2018 06:44 |
Repository Staff Only: item control page
