Porous lanthanide–organic framework with zeolite-like topology

Maji, Tapas Kumar ; Mostafa, Golam ; Chang, Ho-Chol ; Kitagawa, Susumu (2005) Porous lanthanide–organic framework with zeolite-like topology Chemical Communications (19). pp. 2436-2438. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2005...

Related URL: http://dx.doi.org/10.1039/B500971E


Two novel isomorphous porous frameworks of Ln(III), {[Ln2(imidc)2(H2O)3](H2O)}n, [Ln = Gd(III) (1) and Er(III) (2)] have been synthesized hydrothermally using multifunctional 4,5-imidazoledicarboxylic acid (imidc) as a connector; they have a zeolite-like network topology which can provide another form upon dehydration, and exhibit selective adsorption properties for H2O over N2, CO2 and MeOH.

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