5-Exo-dig, 5-exo-trig cascade radical cyclisation on sugar-furanose templates: entry to angularly fused oxa-and dioxa-triquinane skeletons

Gurjar, Mukund K. ; Ravindranadh, S. V. ; Kumar, Punit (2001) 5-Exo-dig, 5-exo-trig cascade radical cyclisation on sugar-furanose templates: entry to angularly fused oxa-and dioxa-triquinane skeletons Chemical Communications . pp. 917-918. ISSN 1359-7345

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Related URL: http://dx.doi.org/10.1039/b101641p

Abstract

Serial radical cyclisation on sugar-furanose templates to create angularly fused oxa- and dioxa-triquinane skeletons has been described, the salient feature of this approach being to incipiently generate a tertiary radical from cyclopropylmethyl bromide with simultaneous release of allyl group and to subsequently incorporate it in the triquinane system.

Item Type:	Article
Source:	Copyright of this article belongs to Royal Society of Chemistry.
ID Code:	11468
Deposited On:	16 Nov 2010 13:55
Last Modified:	16 May 2016 20:55

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