Tunable emission from a porous metal–organic framework by employing an excited-state intramolecular proton transfer responsive ligand

Jayaramulu, K. ; Kanoo, Prakash ; George, Subi J. ; Maji, Tapas Kumar (2010) Tunable emission from a porous metal–organic framework by employing an excited-state intramolecular proton transfer responsive ligand Chemical Communications, 46 (42). pp. 7906-7908. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2010...

Related URL: http://dx.doi.org/10.1039/C0CC02069A

Abstract

A novel molecular design concept to control the emission of a metal–organic framework, {Mg(DHT)(DMF)2}n, (DHT: 2,5-dihydroxyterephthalate), based on excited state proton transfer (ESIPT) of the organic linker, DHT, is demonstrated. The framework unveils permanent porosity and exhibits ligand-based multicolor emission that can be tuned and well controlled by the solvent molecules in solution as well as in the solid state.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:114572
Deposited On:29 May 2018 08:54
Last Modified:29 May 2018 08:54

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