Kanoo, Prakash ; Sambhu, R. ; Maji, Tapas Kumar (2011) Guest-specific double- or single-step adsorption in a flexible porous framework based on a mixed-ligand system Inorganic Chemistry, 50 (2). pp. 400-402. ISSN 0020-1669
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Official URL: https://pubs.acs.org/doi/abs/10.1021/ic101232u
Related URL: http://dx.doi.org/10.1021/ic101232u
Abstract
A 2D flexible metal−organic porous solid, {[Ni(1,3-adc)(bpp)(H2O)2](H2O)(EtOH)}n (1), has been synthesized using flexible organic linkers. The desolvated framework, {[Ni(1,3-adc)(bpp)]}n (1′), undergoes structural contraction and exhibits double-step hysteretic adsorption for CO2, H2O, and MeOH and single-step gate-opening behavior with EtOH. These observations are correlated with the effect of the polarity and window dimension of the pore to the corresponding adsorbate molecules.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 114553 |
| Deposited On: | 29 May 2018 11:24 |
| Last Modified: | 29 May 2018 11:24 |
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