Coordination driven axial chirality in a microporous solid assembled from an achiral linker via in situ C–N coupling

Kanoo, Prakash ; Haldar, Ritesh ; Cyriac, Soumya T. ; Maji, Tapas Kumar (2011) Coordination driven axial chirality in a microporous solid assembled from an achiral linker via in situ C–N coupling Chemical Communications, 47 (39). pp. 11038-11040. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2011...

Related URL: http://dx.doi.org/10.1039/C1CC13877D

Abstract

Metal mediated in situ C–N coupling between 4,4′-azobipyridine and disodium-trans-glutaconate at room temperature has formed a new multifunctional linker ZZ-dhpe which subsequently self-assembles with Zn(II) or Cd(II) resulting in a chiral or an achiral metal–organic framework, respectively, depending on its different coordination modes

Item Type:Article
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