Exciplex formation and energy transfer in a self-assembled metal-organic hybrid system

Haldar, Ritesh ; Venkata Rao, K. ; George, Subi J. ; Maji, Tapas Kumar (2012) Exciplex formation and energy transfer in a self-assembled metal-organic hybrid system Chemistry - A European Journal, 18 (19). pp. 5848-5852. ISSN 0947-6539

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Official URL: http://doi.org/10.1002/chem.201103827

Related URL: http://dx.doi.org/10.1002/chem.201103827

Abstract

Exciting assemblies: A metal–organic self‐assembly of pyrenebutyric acid (PBA), 1,10‐phenanthroline (o‐phen), and MgII shows solid‐state fluorescence originating from a 1:1 PBA–o‐phen exciplex. This exciplex fluorescence is sensitized by another residual PBA chromophore through an excited‐state energy‐transfer process. The solvent polarity modulates the self‐assembly and the corresponding exciplex as well as the energy transfer, resulting in tunable emission of the hybrid.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Energy Transfer; Exciplexes; Hybrid Materials; Pyrene; Self‐Assembly
ID Code:114515
Deposited On:29 May 2018 06:32
Last Modified:29 May 2018 06:32

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