Highly rigid and stable porous Cu(I) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

Mohapatra, Sudip ; Sato, Hiroshi ; Matsuda, Ryotaro ; Kitagawa, Susumu ; Maji, Tapas Kumar (2012) Highly rigid and stable porous Cu(I) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation CrystEngComm, 14 (12). pp. 4153-4156. ISSN 1466-8033

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2012...

Related URL: http://dx.doi.org/10.1039/C2CE06701C

Abstract

A simple room temperature reaction of Cu(NO3)2, and 2,3-pyrazinedicarboxylic acid (H2pyzdc) in the presence of dihydroxyfumaric acid (DHFA) resulted in the formation of a highly stable 3D Cu(I) coordination polymer, {[Cu2(pyzdc)]·0.83H2O}n where DHFA acts as a reducing agent. It possesses a 1D water filled channel along the crystallographic c direction and the framework shows reversible single-crystal-to-single-crystal structural transformation upon dehydration and rehydration.

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ID Code:114510
Deposited On:29 May 2018 08:21
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