Self-assembled superstructure of xanthene derivatives

Kavala, Veerababurao ; Murru, Siva ; Patel, Bhisma K. ; Das, Gopal (2007) Self-assembled superstructure of xanthene derivatives Journal of Chemical Crystallography, 37 (8). pp. 527-535. ISSN 1074-1542

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Various multi carbon homologations of 9-phenyl-9H-xanthen-9-ol (1) were obtained through a C-C bond formation by reacting it with various enolisable ketones in the presence of 1,1′-(ethane-1,2-diyl)dipyridinium bistribromide (EDPBT). All the ten derivatives along with the starting xanthen-9-ol have been characterized by single crystal X-ray diffraction. They all form self-assembled superstructure in the solid state. The self-assembling patterns in these supramolecular architectures were explained based on steric and electronic nature of the pendant arm.

Item Type:Article
Source:Copyright of this article belongs to Springer-Verlag.
Keywords:Supramolecular; Self-assembly; Hydrogen-bonding; Superstructure; Xanthene Derivatives
ID Code:113946
Deposited On:02 May 2018 04:49
Last Modified:02 May 2018 04:49

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