Ratiometric nanomolar detection of Cu2+ ions in mixed aqueous media: A Cu2+/Li+ ions switchable allosteric system based on thiacalix[4]crown

Kumar, Manoj ; Kumar, Naresh ; Bhalla, Vandana (2012) Ratiometric nanomolar detection of Cu2+ ions in mixed aqueous media: A Cu2+/Li+ ions switchable allosteric system based on thiacalix[4]crown Dalton Transactions, 41 (34). pp. 10189-10193. ISSN 1477-9226

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2012...

Related URL: http://dx.doi.org/10.1039/C2DT31081C

Abstract

A novel ditopic fluorescent chemosensor 2, based on the 1,3-alternate conformation of thiacalix[4]crown possessing two complexation sites, was synthesized and shows ratiometric nanomolar detection of Cu2+ ions and exhibits negative allosteric behaviour between Cu2+/Li+ ions in mixed aqueous media.

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