Banerjee, Arghya ; Santra, Sourav Kumar ; Mishra, Aniket ; Khatun, Nilufa ; Patel, Bhisma K. (2015) Copper(I)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3 C–H functionalisation Organic & Biomolecular Chemistry, 13 (5). pp. 1307-1312. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2015...
Related URL: http://dx.doi.org/10.1039/C4OB01962H
Abstract
A copper(I)-promoted cycloalkylation–peroxidation strategy has been developed via a three-component reaction involving cycloalkanes, Tert-butyl Hydroperoxide (TBHP) and internal conjugated alkenes possessing Electron-withdrawing Groups (EWGs). This process installs C–O and C–C bonds via sp3 C–H functionalisation with concomitant generation of two stereocentres. This regioselective radical addition of coumarin system is opposite to that of styrene.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 113821 |
| Deposited On: | 30 Apr 2018 12:13 |
| Last Modified: | 30 Apr 2018 12:13 |
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