Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation

Behera, Ahalya ; Ali, Wajid ; Guin, Srimanta ; Khatun, Nilufa ; Mohanta, Prakash R. ; Patel, Bhisma K. (2015) Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation RSC Advances, 5 (42). pp. 33334-33338. ISSN 2046-2069

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2015...

Related URL: http://dx.doi.org/10.1039/C5RA03836G

Abstract

An oxidative cross-coupling between directing substrates and benzyl bromides via the combined effect of oxidants TBHP and NMO, catalysed by Pd(II) has been investigated. Benzyl bromides served as efficient aroyl surrogates in this substrate directed C–H functionalisation. The in situ generated benzaldehyde originating from benzyl bromide is the active aroylating source.

Item Type:Article
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ID Code:113811
Deposited On:30 Apr 2018 12:13
Last Modified:30 Apr 2018 12:13

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