Synthesis of the putative structure of eupomatilone-6

Gurjar, Mukund K. ; Cherian, Joseph ; Ramana, C. V. (2004) Synthesis of the putative structure of eupomatilone-6 Organic Letters, 6 (3). pp. 317-319. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol035908j

Related URL: http://dx.doi.org/10.1021/ol035908j

Abstract

The synthesis of eupomatilone-6 (1) has been achieved by using Suzuki coupling, sharpless asymmetric dihydroxylation, and intramolecular Horner-Wadsworth-Emmons reactions. The spectroscopic studies carried out on synthetic eupomatilone-6 do not agree with those reported for the natural product, and therefore revision of the assigned structure is warranted.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:11378
Deposited On:09 Nov 2010 05:12
Last Modified:02 Jun 2011 09:47

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