Attogram detection of picric acid by hexa-peri-hexabenzocoronene-based chemosensors by controlled aggregation-induced emission enhancement

Vij, Varun ; Bhalla, Vandana ; Kumar, Manoj (2013) Attogram detection of picric acid by hexa-peri-hexabenzocoronene-based chemosensors by controlled aggregation-induced emission enhancement ACS Applied Materials & Interfaces, 5 (11). pp. 5373-5380. ISSN 1944-8244

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Official URL: https://pubs.acs.org/doi/abs/10.1021/am401414g

Related URL: http://dx.doi.org/10.1021/am401414g

Abstract

Hexa-peri-hexabenzocoronene (HBC) based molecules 5 and 6 have been designed and synthesized. These planar coronenes are appended with rotors to invoke aggregation induced emission enhancement (AIEE) phenomenon by controlling the ratio of H2O in solutions of aggregates. These aggregates of HBC derivatives serve as highly selective chemosensors for picric acid (PA) in mixed aqueous solution. These aggregates are also able to detect PA in vapor phase. In addition, fluorescent test strips have been prepared by dip-coating the Whatman paper with aggregates of both compounds for trace detection of PA in contact mode with detection limits in attograms.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
Keywords:Aggregation Induced Emission Enhancement; Attogram Detection; Hexa-Peri-Hexabenzocoronene; Picric Acid; Vapor Phase Detection
ID Code:113696
Deposited On:18 May 2018 08:12
Last Modified:18 May 2018 08:12

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