Thiacalix[4]crown based optical chemosensor for Fe3+, Li+ and cysteine: A Fe3+/Li+ ion synchronized allosteric regulation

Kumar, Manoj ; Kumar, Naresh ; Bhalla, Vandana (2013) Thiacalix[4]crown based optical chemosensor for Fe3+, Li+ and cysteine: A Fe3+/Li+ ion synchronized allosteric regulation Dalton Transactions, 42 (4). pp. 981-986. ISSN 1477-9226

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2013...

Related URL: http://dx.doi.org/10.1039/C2DT31940C

Abstract

A heteroditopic chemosensor 2 based on a thiacalix[4]crown with a 1,3-alternate conformation has been synthesized and shows a selective fluorescence turn-off response with Fe3+ ions in mixed aqueous media. Furthermore, the 2–Fe3+ complex can be used as a chemosensing system for the detection of Li+ and cysteine based on two different approaches. Moreover, the sequence addition of Fe3+ and Li+ triggers an Fe3+/Li+ switchable on-off-on fluorescence chemosensor with negative allosteric regulations.

Item Type:Article
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ID Code:113638
Deposited On:16 May 2018 05:45
Last Modified:16 May 2018 05:45

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