Chakraborty, Anindita ; Ramachandran, Krishna Kumar ; Yamijala, Sharma S. R. K. C. ; Pati, Swapan K. ; Maji, Tapas Kumar (2014) A hexanuclear Cu(I) cluster supported by cuprophilic interaction: effects of aromatics on luminescence properties RSC Advances, 4 (66). pp. 35167-35170. ISSN 2046-2069
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...
Related URL: http://dx.doi.org/10.1039/C4RA06183G
Abstract
A hexanuclear Cu(I) cluster {Cu3(L)2}2 (1) based on a novel tripodal linker (L) has been synthesized. 1 shows intense emission (λmax = 560 nm) with lifetime 〈τ〉 = 224 μs and quantum yield = 27.6%. The emission is highly sensitive towards different electron rich and electron deficient aromatics. DFT calculations were performed to understand the origin of emission and sensing properties.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 113564 |
| Deposited On: | 29 May 2018 09:18 |
| Last Modified: | 29 May 2018 09:18 |
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