Cascade photocaging of diazeniumdiolate: a novel strategy for one and two photon triggered uncaging with real time reporting

Behara, Krishna Kalyani ; Rajesh, Y. ; Venkatesh, Yarra ; Pinninti, Bhaskar Rao ; Mandal, Mahitosh ; Singh, N. D. Pradeep (2017) Cascade photocaging of diazeniumdiolate: a novel strategy for one and two photon triggered uncaging with real time reporting Chemical Communications, 53 (68). pp. 9470-9473. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2017...

Related URL: http://dx.doi.org/10.1039/C7CC04635A

Abstract

We report a new strategy, viz. cascade photocaging, for protecting diethylamine diazeniumdiolate (O2-position), a light sensitive molecule. Upon photolysis, the cascade photocage at first releases the light activatable linker (latent fluorophore) O2-caged diazeniumdiolate, which undergoes spontaneous 1,8-elimination, triggering the release of the diazeniumdiolate anion and the fluorophore.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:113416
Deposited On:07 May 2018 12:21
Last Modified:07 May 2018 12:21

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