Troger's base molecular scaffolds in dicarboxylic acid recognition

Goswami, Shyamaprosad ; Ghosh, Kumaresh ; Dasgupta, Swagata (2000) Troger's base molecular scaffolds in dicarboxylic acid recognition Journal of Organic Chemistry, 65 (7). pp. 1907-1914. ISSN 0022-3263

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Official URL: https://pubs.acs.org/doi/10.1021/jo9909204

Related URL: http://dx.doi.org/10.1021/jo9909204

Abstract

Artificial receptors (1−5) have been designed and synthesized from simple precursors. The chain length selectivity studies of dicarboxylic acids within the cavities of new fluorescent Troger's base molecular frameworks (1−3) have been carried out with a critical examination of their role of rigidity as well as flexibility in selective binding in comparison to receptor 5. The chiral resolution of the racemic Troger's base receptors (1 and 2) by chiral recognition with (+)- camphoric acid using hydrogen-bonding interactions has been studied.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:113112
Deposited On:15 May 2018 10:53
Last Modified:15 May 2018 10:53

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