Adalikwu, Stephen Adie ; Chakraborty, Anindita ; Hazra, Arpan ; Ghosh, Dibyajyoti ; Pati, Swapan K. ; Maji, Tapas Kumar (2016) 2D coordination polymer composed of 1D {NiII(μ-O)(μ-H2O)NiII}n ferromagnetic chains: Modulation of magnetic properties based on dehydration and rehydration Polyhedron, 115 . pp. 276-281. ISSN 0277-5387
Full text not available from this repository.
Official URL: https://www.sciencedirect.com/science/article/pii/...
Related URL: http://dx.doi.org/10.1016/j.poly.2016.05.011
Abstract
Synthesis, single-crystal structure and magnetic properties of a 2D coordination compound [Ni(1,3-ADA)(H2O)]n (1) is reported which exhibits tunable magnetic behavior based on dehydration–rehydration. 1 shows ferromagnetic (FM) interaction between NiII ions. Combined detailed experimental and theoretical studies reveal that FM interaction arises due to “orthogonal” magnetic orbitals, which become distorted in desolvated state and suppress the FM interaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Coordination Polymer; Magnetism; Dehydration–Rehydration; Guest Responsive Behavior; Density Functional Theory |
| ID Code: | 113030 |
| Deposited On: | 30 May 2018 08:48 |
| Last Modified: | 30 May 2018 08:48 |
Repository Staff Only: item control page
