MOF–aminoclay composites for superior CO2 capture, separation and enhanced catalytic activity in chemical fixation of CO2

Chakraborty, Anindita ; Achari, Amritroop ; Eswaramoorthy, Muthusamy ; Maji, Tapas Kumar (2016) MOF–aminoclay composites for superior CO2 capture, separation and enhanced catalytic activity in chemical fixation of CO2 Chemical Communications, 52 (76). pp. 11378-11381. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2016...

Related URL: http://dx.doi.org/10.1039/C6CC05289D

Abstract

We delineate the growth and stabilization of ultra-small (2–3 nm) {Cu3(BTC)2(H2O)2·xH2O} MOF nanoparticles on a 2D layered aminoclay template. The composite shows significant CO2 uptake (5.35 mmol g−1 at 298 K, 1 bar; 46% higher than pristine bulk MOF), superior CO2 separation efficiency from CO2/N2 and CO2/CH4 mixtures and higher catalytic proficiency for chemical fixation of CO2 into cyclic carbonates.

Item Type:Article
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ID Code:113026
Deposited On:30 May 2018 10:28
Last Modified:30 May 2018 10:28

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