Adarsh, N. N. ; Sahoo, Pathik ; Dastidar, Parthasarathi (2010) Is a crystal engineering approach useful in designing metallogels? A case study Crystal Growth & Design, 10 (11). pp. 4976-4986. ISSN 1528-7483
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Official URL: https://pubs.acs.org/doi/10.1021/cg101078f
Related URL: http://dx.doi.org/10.1021/cg101078f
Abstract
A crystal engineering based design strategy for metallogels has been demonstrated in a series of mixed ligand based CuII/CoII coordination polymers derived from two bis-pyridyl-bis-amide ligands namely N,N′-bis-(3-pyridyl)isophthalamide (L1) and N,N′-bis-(3-pyridyl)terephthalamide (L2) and various dicarboxylates. These mixed ligand coordination polymers are shown to form gels as well as X-ray quality crystals under different conditions. The crystal structures of the gel fibers in the xerogels have been determined by using powder and single-crystal X-ray diffraction data. The results support the proof of the concept based on which the metallogels are designed.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 112522 |
Deposited On: | 19 Apr 2018 11:54 |
Last Modified: | 19 Apr 2018 11:54 |
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