Ascertaining the 1D hydrogen-bonded network in organic ionic solids

Ballabh, Amar ; Trivedi, Darshak R. ; Dastidar, Parthasarathi (2005) Ascertaining the 1D hydrogen-bonded network in organic ionic solids Crystal Growth & Design, 5 (4). pp. 1545-1553. ISSN 1528-7483

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Crystal engineering concepts are exploited to generate a 1D hydrogen-bonded network in a series of organic salts (9−18) derived from dicyclohexylamine and various dicarboxylic acids (1−7) having linear as well as twisted/angular functional topology. It is clearly demonstrated that the cyclic 0D hydrogen-bonded network involving corresponding cations and anions in a secondary ammonium monocarboxylate salt (synthon B or C) can indeed be transformed into a 1D network in 1:2 (acid/amine) dicarboxylate systems (9−12). The effects of the twisted/angular functional topology of the anion moiety on the resultant supramolecular architectures in the corresponding 1:2 (acid/amine) salts (13−15) are examined. The 1:1 salts (16−18) of the dicarboxylic acids having twisted/angular functional topology also display a 1D network.

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Source:Copyright of this article belongs to American Chemical Society.
ID Code:112473
Deposited On:19 Apr 2018 11:48
Last Modified:19 Apr 2018 11:48

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