Ternary alloy nanocatalysts for hydrogen evolution reaction

Saha, Soumen ; Vaidya, Sonalika ; Ramanujachary, Kandalam V. ; Lofland, Samuel E. ; Ganguli, Ashok K. (2016) Ternary alloy nanocatalysts for hydrogen evolution reaction Bulletin of Materials Science, 39 (2). pp. 433-436. ISSN 0250-4707

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Official URL: http://www.ias.ac.in/describe/article/boms/039/02/...

Related URL: http://dx.doi.org/10.1007/s12034-016-1182-2


Cu–Fe–Ni ternary alloys (size ∼55–80 nm) with varying compositions viz. CuFeNi (A1), CuFe2Ni (A2) and CuFeNi2 (A3) were successfully synthesized using microemulsion. It is to be noted that synthesis of nanocrystalline ternary alloys with precise composition is a big challenge which can be overcome by choosing an appropriate microemulsion system. High electrocatalytic activity towards HER in alkaline medium was achieved by the formation of alloys of metals with low and high binding energies. A high value of current density (228 mA cm2) at an overpotential of 545 mV was obtained for CuFeNi (A1), which is significantly high as compared to the previously reported Ni59Cu41 alloy catalyst.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Nanostructures; Chemical Synthesis; Electrochemical Measurements
ID Code:112067
Deposited On:28 Sep 2017 12:22
Last Modified:28 Sep 2017 12:22

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