Yadav, G. D. ; Mistry, C. K. (1995) A new model of capsule membrane phase transfer catalysis for oxidation of benzyl chloride to benzaldehyde with hydrogen peroxide Journal of Molecular Catalysis A: Chemical, 102 (2). pp. 67-72. ISSN 1381-1169
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Official URL: http://www.sciencedirect.com/science/article/pii/1...
Related URL: http://dx.doi.org/10.1016/1381-1169(95)90041-1
Abstract
This work deals with the theoretical and experimental aspects of the capsule membrane supported phase transfer catalysed (CM-PTC) oxidation of benzyl chloride to benzaldehyde using hydrogen peroxide (H2O2) as the oxidizing agent. A new model is proposed for the CM-PTC oxidation of benzyl chloride using H2O2 wherein the nucleophile (H2O2) is transferred from the aqueous phase to the organic phase as a solvate of the catalyst which is supported on the capsule surface. This Langmuir-Hinshelwood type of model with the anchored-quaternary-H2O2 complex as the active site was found to govern the rate of reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 111956 |
| Deposited On: | 18 Sep 2017 12:25 |
| Last Modified: | 18 Sep 2017 12:25 |
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