Yadav, Ganapati D. ; Thorat, Tushar S. (1996) Role of benzyl ether in the inversion of reactivities in Friedel-Crafts benzylation of toluene by benzyl chloride and benzyl alcohol Tetrahedron Letters, 37 (30). pp. 5405-5408. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4039(96)01057-X
Abstract
In the inversion in the reactivities and selectivities of benzyl chloride (BnCl) and benzyl alcohol (BnOH) in a single pot Friedel-Crafts benzylation with toluene, there is not only a preferential adsorption of benzyl alcohol on the solid acid catalyst but also a second preference to the adsorption of benzyl ether (BE) formed in-situ. The order of prefential adsorption is BnOH > BE > BnCl. The preferential adsorption order for the benzylation of toluene with benzyl chloride and benzyl alcohol in a single pot situation is, BnOH > BE > BnCl.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Friedel-Crafts; Inversion; Benzylation; Preferential Adsorption; Solid Catalysts |
| ID Code: | 111953 |
| Deposited On: | 18 Sep 2017 12:25 |
| Last Modified: | 18 Sep 2017 12:25 |
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