Redox-active metal-organic composites for highly selective oxygen separation applications

Zhang, Wen ; Banerjee, Debasis ; Liu, Jian ; Schaef, Herbert T. ; Crum, Jarrod V. ; Fernandez, Carlos A. ; Kukkadapu, Ravi K. ; Nie, Zimin ; Nune, Satish K. ; Motkuri, Radha K. ; Chapman, Karena W. ; Engelhard, Mark H. ; Hayes, James C. ; Silvers, Kurt L. ; Krishna, Rajamani ; Peter McGrail, B. ; Liu, Jun ; Thallapally, Praveen K. (2016) Redox-active metal-organic composites for highly selective oxygen separation applications Advanced Materials, 28 (18). pp. 3572-3577. ISSN 0935-9648

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adma.20...

Related URL: http://dx.doi.org/10.1002/adma.201600259

Abstract

A redox-active metal–organic composite material shows improved and selective O2 adsorption over N2 with respect to individual components (MIL-101 and ferrocene). The O2 sensitivity of the composite material arises due to the formation of maghemite nanoparticles with the pore of the metal–organic framework material.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Composite Materials; Redox-Active; Metal–Organic Frameworks; Oxygen Sensors; Oxygen Separation
ID Code:111928
Deposited On:25 Sep 2017 13:05
Last Modified:25 Sep 2017 13:05

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