Kinetics of epoxidation of alkyl esters of undecylenic acid: comparison of traditional routes vs. ishii-venturello chemistry

Yadav, G. D. ; Satoskar, D. V. (1997) Kinetics of epoxidation of alkyl esters of undecylenic acid: comparison of traditional routes vs. ishii-venturello chemistry Journal of the American Oil Chemists' Society, 74 (4). pp. 397-407. ISSN 0003-021X

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Official URL: https://link.springer.com/article/10.1007/s11746-9...

Related URL: http://dx.doi.org/10.1007/s11746-997-0097-x

Abstract

Epoxidation of undecylenic acid and its methyl and ethyl esters with aqueous H2O2 was carried out by using different traditional routes, ion exchange resin, and the newly developed synergistic usage of heteropoly acids and phase transfer catalysis in a biphasic system. The so-called Ishii-Venturello chemistry was employed to develop a kinetic model. Interesting selectivities are obtained.

Item Type:Article
Source:Copyright of this article belongs to Springer-Verlag.
Keywords:Catalysis; Epoxidation; Ethyl Undecylenate; Heteropoly Acids; Ishii-Venturello Chemistry; Kinetics; Methyl Undecylenate; Peroxyacetic Acid; Phase Transfer Catalysis; Undecylenic Acid
ID Code:111927
Deposited On:18 Sep 2017 12:24
Last Modified:18 Sep 2017 12:24

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