Tracing the origins of transient overshoots for binary mixture diffusion in microporous crystalline materials

Krishna, Rajamani (2016) Tracing the origins of transient overshoots for binary mixture diffusion in microporous crystalline materials Physical Chemistry Chemical Physics, 18 (23). pp. 15482-15495. ISSN 1463-9076

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2016...

Related URL: http://dx.doi.org/10.1039/C6CP00132G

Abstract

Separation of mixtures using microporous crystalline materials is normally achieved by exploiting differences in the adsorption strengths of the constituent species. The focus of the current investigation is on diffusion-selective separations that exploit differences in intra-crystalline diffusivities of guest molecules. A number of experimental investigations report overshoots in intra-crystalline loadings of the more mobile species during transient mixture uptake. Analogous overshoots in fluxes occur for mixture permeation across thin microporous membrane layers. The attainment of supra-equilibrium loadings is a common characteristic of diffusion-selective separations; this allows the over-riding of adsorption selectivities. The primary objective of the current investigation is to demonstrate that the Maxwell–Stefan diffusion formulation, using chemical potential gradients as driving forces, is capable of providing a quantitative description of the temporal and spatial overshoots found in diverse experimental studies. The origins of the overshoots can be traced to thermodynamic coupling effects that emanate from sizable off-diagonal contributions of the matrix of thermodynamic correction factors. If thermodynamic coupling effects are neglected, the overshoots are not realized. It is also demonstrated that while the transport of the more mobile partner is uphill of its loading gradient, its transport is downhill the gradient of its chemical potential. The deliberate exploitation of uphill diffusion to achieve difficult separations is highlighted.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:111910
Deposited On:26 Sep 2017 12:56
Last Modified:26 Sep 2017 12:56

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