Yadav, G. D. ; Naik, Suguna S. (2000) Clay-supported liquid−liquid−solid phase transfer catalysis: synthesis of benzoic anhydride Organic Process Research & Development, 4 (3). pp. 141-146. ISSN 1083-6160
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/op990087c?jour...
Related URL: http://dx.doi.org/10.1021/op990087c
Abstract
Solid-supported phase transfer catalysed reactions typically involve polystyrene supports cross-linked with divinyl benzene. The use of commercially available clay as a support for the PTC reaction is attractive. This paper reports the preparation of benzoic anhydride from benzoyl chloride and sodium benzoate using clay-supported quaternary ammonium salts at 30 °C. The selectivity to the product is 100%. The mechanistic and kinetic aspects are also reported. The clay-supported catalyst was found to be more active than polymer-supported catalysts.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 111872 |
| Deposited On: | 15 Sep 2017 13:21 |
| Last Modified: | 15 Sep 2017 13:21 |
Repository Staff Only: item control page
