Novelties of liquid–liquid–liquid phase transfer catalysis: alkoxylation of p-chloronitrobenzene

Yadav, G. D. ; Naik, Suguna S. (2001) Novelties of liquid–liquid–liquid phase transfer catalysis: alkoxylation of p-chloronitrobenzene Catalysis Today, 66 (2-4). pp. 345-354. ISSN 0920-5861

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0920-5861(00)00630-1

Abstract

Liquid–liquid–liquid phase transfer catalysis (L–L–L PTC) offers orders of magnitude intensification of rates of reaction and better selectivities than the biphasic PTC. The catalyst-rich middle phase is the main reaction phase. The etherification or alkoxylation of p-chloronitrobenzene (PCNB) was conducted by using alkanol and alkali instead of the metal alkoxide. A kinetic model is presented and validated.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Alkoxylation; p-Chloronitrobenzene; Phase Transfer Catalysis; Liquid–Liquid–Liquid System
ID Code:111867
Deposited On:18 Sep 2017 12:23
Last Modified:19 Sep 2017 11:13

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