Entropic separations of mixtures of aromatics by selective face-to-face molecular stacking in one-dimensional channels of metal-organic frameworks and zeolites

Torres-Knoop, Ariana ; Balestra, Salvador R. G. ; Krishna, Rajamani ; Calero, Sofía ; Dubbeldam, David (2015) Entropic separations of mixtures of aromatics by selective face-to-face molecular stacking in one-dimensional channels of metal-organic frameworks and zeolites ChemPhysChem, 16 (3). pp. 532-535. ISSN 1439-4235

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/cphc.20...

Related URL: http://dx.doi.org/10.1002/cphc.201402819

Abstract

Separation of challenging mixtures using metal–organic frameworks can be achieved by an entropy-driven mechanism, where one of the components can arrange into a “face-to-face” stacking, thus reducing its “footprint” and reaching a higher saturation loading.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Aromatic Compounds; Entropy; Mixtures; MOFs; Separation
ID Code:111683
Deposited On:25 Sep 2017 13:05
Last Modified:25 Sep 2017 13:05

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