Gauche and staggered forms of diethylamine in solvates of 1,5-dichloro-cis-9,10-diethynyl-9,10-dihydroanthracene-9,10-diol. A case of conformational pseudopolymorphism?

Mondal, Raju ; Howard, Judith A. K. ; Banerjee, Rahul ; Desiraju, Gautam R. (2004) Gauche and staggered forms of diethylamine in solvates of 1,5-dichloro-cis-9,10-diethynyl-9,10-dihydroanthracene-9,10-diol. A case of conformational pseudopolymorphism? Chemical Communications (6). pp. 644-645. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2004...

Related URL: http://dx.doi.org/10.1039/B316270B

Abstract

Diethylamine has been trapped in its less stable gauche conformation in a solvate of the title diol; the staggered conformation, which is ca. 4 kJ mol-1 more stable, is found in another solvate of the same host.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:11114
Deposited On:08 Nov 2010 07:05
Last Modified:16 May 2016 20:37

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