A crystallographic scale of carbon acidity

Pedireddi, V. R. ; Desiraju, Gautam R. (1992) A crystallographic scale of carbon acidity Chemical Communications (14). pp. 988-990. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1992...

Related URL: http://dx.doi.org/10.1039/C39920000988


For several carbon acids C-H, mean C-H···O distances in 551 crystal structures correlate well with conventional pKa(Me2SO) values, thus furnishing a new scale of carbon acidity.

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