Strength and linearity of C-H···O bonds in molecular crystals: a database study of some terminal alkynes

Desiraju, Gautam R. (1990) Strength and linearity of C-H···O bonds in molecular crystals: a database study of some terminal alkynes Chemical Communications (6). pp. 454-455. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1990...

Related URL: http://dx.doi.org/10.1039/C39900000454

Abstract

An analysis of 105 and 622 C-H···O bond geometries retrieved from 69 alkyne and 131 alkene structures in the Cambridge Structural Database shows that more acidic C-H groups tend to form stronger bonds but that even weak C-H···O bonds have pronounced linearity.

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ID Code:11016
Deposited On:09 Nov 2010 04:16
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