Verma, Pritha ; Verma, Pragya ; Sunoj, Raghavan B. (2014) The mechanism of the NHC catalyzed aza-Morita–Baylis–Hillman reaction: insights into a new substrate-catalyzed bimolecular pathway Organic and Biomolecular Chemistry, 12 (14). pp. 2176-2179. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...
Related URL: http://dx.doi.org/10.1039/C3OB42273A
Abstract
The first mechanistic study on the NHC-catalyzed aza-MBH reaction between cyclopentenone and N-mesylbenzaldimine using density functional theory reveals that a bimolecular mechanism, involving two molecules of benzaldimine in the proton transfer, is energetically more preferred over the conventional direct proton transfer.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 109751 |
| Deposited On: | 02 Aug 2017 11:59 |
| Last Modified: | 03 Aug 2017 05:36 |
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