Saravanakumar, Rajendran ; Varghese, Babu ; Sankararaman, Sethuraman (2009) Hydrogen-bond network in isomeric phenylenedipropynoic acids and their DABCO salts. Water mediated helical hydrogen bond motifs CrystEngComm, 11 (2). pp. 337-346. ISSN 1466-8033
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/2009...
Related URL: http://dx.doi.org/10.1039/B816658G
Abstract
The crystal structures of isomeric phenylenedipropynoic acids (PPA) are reported. 1,2-PPA shows an intra- and intermolecular hydrogen bonded 2D layered sheet structure. 1,4-PPA also has a 2D layered sheet structure. However the hydrogen bond is mediated by water molecules in the lattice. 1,3-PPA has an interpenetrating 3D structure without any void. The lattice of 1,3-PPA consists of two types of helical hydrogen bond network mediated by water molecules. The crystal structures of the DABCO salts of the 1,2-PPA and 1,4-PPA also show an interesting 3D and 2D hydrogen bond network, respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 109655 |
| Deposited On: | 02 Aug 2017 12:40 |
| Last Modified: | 02 Aug 2017 12:40 |
Repository Staff Only: item control page
