Crystal engineering via Cl ··· Cl non-bonded interactions. The novel 2:1 complex, 6-chloro-3,4-(methylenedioxy)cinnamic acid-2,4-dichlorocinnamic acid. Topochemical conversion into an unsymmetrical cyclobutane and kinetics of the reaction

Sarma, Jagarlapudi A. R. P. ; Desiraju, Gautam R. (1984) Crystal engineering via Cl ··· Cl non-bonded interactions. The novel 2:1 complex, 6-chloro-3,4-(methylenedioxy)cinnamic acid-2,4-dichlorocinnamic acid. Topochemical conversion into an unsymmetrical cyclobutane and kinetics of the reaction Chemical Communications (3). pp. 145-147. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1984...

Related URL: http://dx.doi.org/10.1039/C39840000145

Abstract

Two chloro-subsitituted cinnamic acids have been induced to co-crystallise as a molecular complex which is converted, at different rates, into an unsymmetrical and two symmetrical cyclobutanes during solid-state topochemical 2 + 2 photoaddition.

Item Type:Article
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