Solid state thermal phase transitions and decompositions of nickel (II) diamine complexes

Ghosh, Ashutosh ; De, Goutam ; Chaudhuri, Nirmalendu Ray (1985) Solid state thermal phase transitions and decompositions of nickel (II) diamine complexes Thermochimica Acta, 92 . pp. 759-762. ISSN 0040-6031

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0040-6031(85)85988-8

Abstract

[NiL2X2] and [NiL2Br2] •2H2O complexes (L = N, N'-dimethyl 1,2-ethanediamine and XCl, SCN, CF3COO− and CCl3COO−) have been synthesised and their TG-DTA/DSC studies have been carried out. Thermally induced-phase transition phenomena of [NiL2X2] (X = SCN, CF3COO and CCl3COO) are noticed and their probable mechanisms explored. Solid state synthesis of [NiLCl2] and [NiL2Cl2] is achieved through pyrolysis of [NiL2Cl2] and [NiL2 (OOCCCl3)2] respectively.

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