First structural characterisation of nitro–nitrito linkage isomers of nickel (II): synthesis and single crystal structures of [NiL2(NO2)2] and [NiL2(ONO)2] [L = 1-(2-aminoethyl)piperidine]

Das, Debasis ; Laskar, Inamur Rahaman ; Ghosh, Ashutosh ; Mondal, Arunendu ; Okamoto, Ken-ichi ; Chaudhuri, Nirmalendu Ray (1998) First structural characterisation of nitro–nitrito linkage isomers of nickel (II): synthesis and single crystal structures of [NiL2(NO2)2] and [NiL2(ONO)2] [L = 1-(2-aminoethyl)piperidine] Journal of the Chemical Society, Dalton Transactions (23). pp. 3987-3990. ISSN 0300-9246

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1998...

Related URL: http://dx.doi.org/10.1039/A806858E

Abstract

The linkage isomers trans-bis[1-(2-aminoethyl)piperidine]dinitronickel (II) (brown) 1 and trans-bis[1-(2-aminoethyl)piperidine]dinitritonickel (II) (blue) 2 have been synthesized and characterised by X-ray single crystal structure analysis.

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