Synthesis and characterization of cis and trans isomers of [NiL2(NCS)2] [L=1-(2-aminoethyl)pyrrolidine]: X-ray single-crystal structures

Laskar, Inamur Rahaman ; Maji, Tapas Kumar ; Chaudhuri, Siddhartha ; Ghosh, Ashutosh ; Chaudhuri, Nirmalendu Ray (2000) Synthesis and characterization of cis and trans isomers of [NiL2(NCS)2] [L=1-(2-aminoethyl)pyrrolidine]: X-ray single-crystal structures Polyhedron, 19 (15). pp. 1803-1807. ISSN 0277-5387

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0277-5387(00)00476-9

Abstract

The isomeric complexes trans-[NiL2(NCS)2] (violet) (1) and cis-[NiL2(NCS) 2] (blue) (2) [L=1-(2-aminoethyl)pyrrolidine] have been synthesized, varying solvents and temperature, and their X-ray crystal structures have been determined. Both the isomers possess the same space group, P21/c, having distorted octahedral geometry.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Nickel(II)thiocyanate; 1-(2-Aminoethyl)pyrrolidine; Crystal Structures; Cis/trans Isomers
ID Code:108414
Deposited On:13 Oct 2017 13:08
Last Modified:13 Oct 2017 13:08

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