A new tetrameric CuII cluster with square topology exhibiting ferro- and antiferromagnetic magnetic pathways: which is which?

Ray, Mau Sinha ; Ghosh, Ashutosh ; Das, Ansuman ; Drew, Michael G. B. ; Ribas-Arino, Jordi ; Novoa, Juan ; Ribas, Joan (2004) A new tetrameric CuII cluster with square topology exhibiting ferro- and antiferromagnetic magnetic pathways: which is which? Chemical Communications (9). pp. 1102-1103. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2004...

Related URL: http://dx.doi.org/10.1039/B401061B

Abstract

[Cu4L2(bpy)4(H2O)3](ClO4)4•2.5H2O, 1, a new tetranuclear CuII cluster showing square planar geometry, formed with aspartate bridging ligand (L) has been synthesized. The global magnetic coupling is ferromagnetic but theoretical DFT/B3LYP calculations are necessary to assign which Cu–L–Cu side is ferro or antiferromagnetically coupled.

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