Facile synthesis of enantiopure chiral molecular rectangles exhibiting induced circular dichroism

Das, Neeladri ; Ghosh, Ashutosh ; Singh, Okram M. ; Stang, Peter J. (2006) Facile synthesis of enantiopure chiral molecular rectangles exhibiting induced circular dichroism Organic Letters, 8 (8). pp. 1701-1704. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol060365%2B

Related URL: http://dx.doi.org/10.1021/ol060365+

Abstract

The facile syntheses of enantiopure molecular rectangles using 1,8-bis(trans-Pt(Pet3)2(NO3))anthracene and optically pure D- or L-tartrate are reported in high yields. These self-assembled macrocycles are unique examples where the phenomenon of Induced Chiral Dichroism (ICD) has been observed in chiral metallosupramolecular assemblies.

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