Chattopadhyay, Shouvik ; Bocelli, Gabriele ; Musatti, Amos ; Ghosh, Ashutosh (2006) First oxidative synthetic route of a novel, linear mixed valence Co(III)Co(II)Co(III) complex with bridging acetate and salen Inorganic Chemistry Communications, 9 (10). pp. 1053-1057. ISSN 1387-7003
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2006.06.017
Abstract
A linear, trinuclear mixed valence complex [CoII{(μ-L)(μ-OAc)CoIII(NCS)}2] has been prepared and its molecular structure has been elucidated on the basis of X-ray crystallography [H2L = salen = 1,6-bis(2-hydroxyphenyl)-2,5-diazahexa-1,5-diene]. The complex contains a high-spin CoII and two terminal low-spin CoIII, i.e., it is a CoIII(S = 0) CoII(S = 3/2) CoIII(S = 0) trimer.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Mixed Valence; Co(II) and Co(III); Salen; Bridging Acetate; Trinuclear; Crystal Structure |
| ID Code: | 108383 |
| Deposited On: | 17 Oct 2017 12:59 |
| Last Modified: | 17 Oct 2017 12:59 |
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